Are there extended hours sessions (pre/post market) for options trading?
No, extended sessions are available for stocks, but not options. You can only trade options from 9:30am-4pm EST M-F.
If you ever get assigned on an option position and need to get rid of your resulting stock position, in that case, you could take advantage of extended trading hours to buy or sell the stock. See Module 6: How To Manage Losing Trades for detailed step-by-step on how to get rid of assigned option positions.